Chemistry plays a significant role in the emerging interdisciplinary fields
of nanoscience and nanotechnology. The nanoscale refers to materials with
dimensions on the scale of nanometers (a thousandth of a thousandth of
a thousandth of a meter). Control of the material world at the scale of
atoms and molecules can produce materials with fundamentally different
properties and behavior and has been touted as the next technological revolution.
Some questions we will consider include: What nanotechnology already exists?
What makes nanomaterials special? How can they be prepared? What tools
can be used to study such materials?
Prerequisite: Chemistry 117
| Spring 2007 | Nanochemistry |
Lisensky |
| Jan 17 | Ozin, Preface and aims (pages v-xii) |
| Jan 19 | Ozin, Chapter 1 Nanomaterials are small enough in at least one dimension that the properties are different from bulk properties. Monodispersed particles have a relatively narrow size distribution. |
| Jan 22 | Class: Nanochemistry Basics Lab: Self-assembled monolayers. We will do the procedure more than once. Think how you could do some patterning, perhaps like Figure 1.18 in Ozin. Masking or using a razor blade on the silver layer is one way. Lab: Colloidal Magnetite Nanoparticles (ferrofluid). You will need to bring a bound laboratory notebook and either safety glasses or $2. Your record of your work will be graded during the lab period (see handout for the appropriate format.) |
| Jan 24 | Literature reports Choose a nano article from Nanoletters (see especially the most cited or most accessed list), Materials Today, or one referenced in the Materials News (we only have subscriptions to some of the links in the latter.) Summarize the paper in a short oral report, focusing primarily on a figure or two in the paper. Email your claim a paper by including a link to the abstract. |
| Jan 26 | Ozin, Chapter 2 |
| Jan 29 | Class: Lithography Lab: Electrochromic Prussian Blue Thin Films Lab: Electrochromic Prussian Blue Pixels |
| Jan 31 | Literature reports Stephen: Molecular Surgery Using Gene-Specific Positioned Metal Nanoparticles as Laser Light Antennas, Nano Lett. (2007) ASAP Article Tanishka: Taking Nanolithography Beyond Semiconductors, Advanced Materials, 18(24), 3258, 2006 or PhysOrg Jhaunell: Nanopolymers make their debut, Science 315, 358, 2007 or Physics Web Annemarie: Nanowire Photonics, Materials Today, 9(10), 2006 Grisha: Stabilization of liposomes through enzymatic polymerization of DNA, Nano Lett., 6(12), 2755, 2006 Travis: Nanoscopically Flat Open-Ended Single-Walled Carbon Nanotube Substrates, Nano Lett., 7(1), 15 -21, 2007 Kyle: Nanorobotic Spot Welding: Controlled Metal Deposition from Copper-Filled Carbon Nanotubes, Nano Lett., 7(1), 58 -63, 2007 Zeke: Hydrogen Sieving and Storage in Fullerene Intercalated Graphite, Nano Lett., 7(1), 1-5 (2007) Xiaoyue: DNA Nucleoside Interaction and Identification with Carbon Nanotubes, Nano Lett., 7(1), 45-50, 2007 |
| Feb 2 | Ozin, Chapter 3 |
| Feb 5 | Class: Diffraction Lab: PDMS |
| Feb 7 | Literature reports |
| Feb 9 | Ozin, Chapter 4 |
| Feb 12 | Class: Scanning
Probe Microscopies Lab: Nanowires (finish PDMS) |
| Feb 14 | Literature reports Xiaoyue: Single-Crystalline Branched Nanowire Heterostructures, Nano Lett., 7 (2), 264 -268, 2007 Jhaunell: Nanometals, Materials Today, 7(2), 26-31 (2004). Annemarie: Nanowire Photonics, Materials Today, 9(10), 2006 Stephen: Electrochemical Nanoimprinting with Solid-State Superionic Stamps, Nano Lett., 7 (2), 446-451, (2007) |
| Feb 16 | Ozin, Chapter 5 (to page 199) |
| Feb 19 | Class: Carbon Nanotubes Lab: Y2O3:Eu (finish Nanowires, SEM Photos) |
| Feb 21 | Literature reports (email reference to claim a paper by including a link to the abstract) |
| Feb 23 | Ozin, Chapter 5 (page 199 to CNT) |
| Feb 26 | Class: Semiconductors Lab: finish Y2O3:Eu Seminar at 4:00, Nanoscale Technologies for the Realization of Rapid, Cost Effective Individual Genotyping |
| Feb 28 | Literature reports (email reference
to claim a paper by including a link to the abstract)
Xiaoyue: Rings of Single-Walled Carbon Nanotubes, Nano Lett., 7 (2), 276 -280, 2007 Jhaunell: Nanorust Cleans Arsenic from Drinking Water, http://www.photonics.com/content/news/2006/November/13/85089.aspx, Science, 314, 964-967, Nov 10, 2006. Annemarie: Anticancer nanoparticles, http://www.technologyreview.com/Nanotech/18066/, PNAS 104(3), 932-6, 2007 (Jan 16) Stephen: Single-Walled Carbon Nanotube Scaffolds for Photoelectrochemical Solar Cells, Nano Lett., ASAP 02/20/2007 |
| Mar 2 | Ozin, Chapter 5 (CNT to end) |
| MIDTERM BREAK | |
| Mar 12 | No Class or lab today |
| Mar 14 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Mar 16 | Ozin, Chapter 6 (first part) |
| Mar 19 | Class: Particle
in a Box, 1-D
Quantum States, Quantum Dots Lab: CdSe Quantum Dots |
| Mar 21 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Mar 23 | Ozin, Chapter 6 (second part) |
| Mar 26 | Class: Barcode
methods Lab: Gold and Silver Nanoparticles (3 experiments) Au/citrate Au/photoreactor Ag/borohydride |
| Mar 28 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Mar 30 | Nanoscale Demonstrations and Activities. See links at bottom of page. Watch training vidoes and/or read activity guide. |
| Apr 2 | Class: Photonics Lab: Opals and Particle size |
| Apr 4 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Apr 6 | Ozin, Chapter 7 |
| Apr 9 | Class: Nano board game Lab: Inverse Opals |
| Apr 11 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Apr 13 | Hand in game evaluation |
| Apr 16 |
Hand in new decision game card |
| Apr 19-21 | Engineering Expo |
| Apr 23 | Class: Solar Cells Lab: Titanium Dioxide Raspberry Solar Cells |
| Apr 25 | Literature reports (email reference
to claim a paper by including a link to the abstract)
|
| Apr 27 | Ozin, Chapter 9
and 10
Inner Life of the Cell |
| Apr 30 | Class: Societal
Implications KQED: Nanotechnology Takes Off Lab: Liquid Crystal Sensors and Lab Check Out |
| May 2 | Ozin, Chapter 11 |
Literature Sources
Nanoletters (American
Chemical Society)
Materials Today (Elsevier)
NanoToday (Elsevier)
Materials News (Materials
Research Society)
Texts
Nanochemistry: A Chemical Approach to Nanomaterials, Geoffrey Ozin
and André Arsenault, Royal Society of Chemistry (2005).
Lab Manual for Nanoscale Science and Technology, Interdisciplinary
Education Group, http://mrsec.wisc.edu/edetc/nanolab/ (2007).
Future Technology, Today's Choices, Greenpeace, http://www.greenpeace.org.uk/ (2003).
No small matter: The case for a global moratorium, ETC group, http://www.etcgroup.org/documents/Occ.Paper_Nanosafety.pdf (2003).
There’s Plenty of Room at the Bottom, Richard Feynman, http://www.zyvex.com/nanotech/feynman.html (1959).
Basis of evaluation
• Class participation based on text readings.
• Presentations based on literature article (every other week).
• Laboratory reports.
• Reflection on participation in the Engineering Expo.